How can I solve the Nernst equation?

1 Answer
May 14, 2016

E_(cell)=E_(cell)^@-(RT)/(nF)lnQEcell=EcellRTnFlnQ

Explanation:

The Nernst Equation is the following:

E_(cell)=E_(cell)^@-(RT)/(nF)lnQEcell=EcellRTnFlnQ

Where,
nn is the number of mole electrons exchanged during the redox reaction,
F=96485C/("mol "e^-)F=96485Cmol e is Faraday's constant.
R=8.3145J/(K*mol)R=8.3145JKmol is the ideal gas law constant,
TT is the Kelvin temperature,
and QQ is the reaction quotient.

For example, consider the following reaction:

2Al(s)+3Mn^(2+)(aq)->2Al^(3+)(aq)+3Mn(s)2Al(s)+3Mn2+(aq)2Al3+(aq)+3Mn(s)

the Nernst equation would be:

E_(cell)=E_(cell)^@-(RT)/(nF)ln(([Al^(3+)]^2)/([Mn^(2+)]^3))Ecell=EcellRTnFln[Al3+]2[Mn2+]3

Here is a video that explains more about the Nernst equation, I hope you find it helpful:
Electrochemistry | The Concentration Cell.