Question #1cf45

1 Answer
Aug 14, 2017

40,0%

Explanation:

Oleum 109 % in sulfuric acid means that in 100 g of oleum there is enough SO_3 to make 109 grams of sulfuric acid, once you add the same amount of water in moles, following the reaction:

SO_3 + H_2O -> H_2SO_4

If x is the unknown mass percentage of SO_3, the moles in it must correspond to 9 + x grams of sulfuric acid.

Given the ratio between molar masses of SO_3 and H_2SO_4, that is f = 80.066/98.079 = 0.81634 we have the following mass equation:

x/f = x + 9g

That means: the grams of SO_3 in 100 grams of oleum, when transformed in H_2SO_4 (dividing by f) must become x + 9 grams of sulfuric acid.

This is to minimize algebra and maximize logical and qualitative thinking.

Rearranging the equation to find x we get:

x = 9g*f/(1 - f) = 9g*0.81634/(1-0.81634) = 40.00 g

In fact, if you divide the resulting 40 grams of SO_3 by the factor f = 0.81634 you get 49.00 grams of sulfuric acid as the corresponding amount in moles.