Why is CuI2 unstable?

1 Answer
Feb 26, 2018

CuI_2CuI2 will have a redox reaction

Explanation:

If we bring together Cu^(2+)Cu2+ and I^-I ions the copper(II) will be reduced to copper(I), while part of the iodide will be oxidized to iodine.
Copper(I)iodide is badly soluable:

2Cu^(2+)(aq)+4I^-(aq) -> 2CuI(s)+I_2(aq)2Cu2+(aq)+4I(aq)2CuI(s)+I2(aq)

The partial reactions being:
2Cu^(2+)(aq)+2e^(-) ->2Cu^+(aq)2Cu2+(aq)+2e2Cu+(aq) = reduction
2I^(-)(aq) ->I_2(aq)+2e^-2I(aq)I2(aq)+2e = oxidation
2Cu^+(aq) +2I^(-)(aq)->2CuI(s)2Cu+(aq)+2I(aq)2CuI(s) = precipitation