If 0.248 mg of MgF2 is the maximum quantity that can be dissolved in 0.5 L of 0.1 Μ KF, what will be the Ksp of MgF2 under the same conditions?

1 Answer
Mar 8, 2018

We are provided with a solubility, which means we need an ICE table to solve this. Let's write out the net ionic equation, but with the solid as the reactant.

MgF2Mg2++2F

Initially, the concentration of Mg is 0M and the concentration of F is already 0.1M

Then at equilibrium, we subtract variable s from MgF2 and add s to both other values.

This gives us

MgF2=S
Mg2+=+S
2F=0.1+S

Since we know that S is in mol / L, we must take the given mass and turn it into moles, then divide by L.

So...

0.000248g62.3018(gmol)=0.00000398molMgF2

0.00000398mol0.5L=0.00000796M

And...

Ksp=Products1=[S(0.1+S)]=0.1S+S2

S is already 0.00000796 M, so we just plug this in

0.10.00000796M+0.00000796M2

This means that the Ksp is 0.000000796

Or, in scientific notation: 7.96107