What is the cofficient of Cr^2+?

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1 Answer
Apr 11, 2018

2Cr2+

Explanation:

Start by finding what has been oxidized and what has bee reduced by inspecting the oxidation numbers:

In this case:
Cr2+(aq)Cr3+(aq)
Is the oxidation
and
SO24(aq)H2SO3(aq)
is the reduction
Start by balancing the half equations for oxygen by adding water:

SO24(aq)H2SO3(aq)+H2O(l)
(Only the reduction includes oxygen)

Now balance hydrogen by adding protons:

4H+(aq)+SO24(aq)H2SO3(aq)+H2O(l)
(again, only the reduction involves hydrogen)

Now balance each half-equation for charge by adding electrons to the more positive side:
Cr2+Cr3++e

4H++SO24(aq)+2eH2SO3(aq)+H2O(l)

And to equalize the electrons, multiply the whole half equation with the least electrons by an integer to equal the other half-equation in the number of electrons, thereby balancing the electrons on both sides of the equation:

2Cr2+2Cr3++2e

Now combine everything and remove the electrons (as they in equal amounts on both sides they can be canceled in this step - otherwise just simplify as far as possible)

4H+(aq)+SO24(aq)+2Cr2+(aq)2Cr3+(aq)+H2SO3(aq)+H2O(l)

Now the equation is balanced and we can see that the coefficient to Cr2+ is 2.