How do exothermic reactions occur?

1 Answer
Apr 22, 2018

|EnthalphyBondF|>|EnthalphyBondB|

Explanation:

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In any reaction, there is two stages. The Bond Breaking ** and Bond Forming** stage which occurs after bond breaking.

Lets take N2+3H2=NH3 as reaction for example. This reaction ,common in the Haber Process, is exothermic. Why? Simply , energy is first used to break the bonds of NN in N2 and H=H in H2. Let this energy 'absorbed' be |EnthalphyBondB| .

After that, free N atoms and free H atoms collide to form NH single bonds in newly formed NH3. Let this energy 'released' be |EnthalphyBondF| .

Since in this reaction, the energy evolved(released) is larger than the energy absorbed to break the bonds, there is a net release of energy which results in the products having a lower energy content than the reactants as shown in the graph.

aka |EnthalphyBondF| > |EnthalphyBondB|