P+Naoh + H2O = PH3 + NaH2PO2 How to balance it?

1 Answer
May 4, 2018

#P + 3NaOH + 3H_2O# #-># #PH_3# + #3NaH_2PO_2#

Explanation:

let's say:

#(a)P + (b)NaOH + (c)H_2O# #-># #(d)PH_3# + #(e)NaH_2PO_2#
we can know:
a = d (number of Phosphorus atoms must be the same)
b = e (number of Sodium atoms must be the same)
b + c = 2e (number of Oxygen atoms must be the same)
b + 2c = 3d + 2e (number of Hydrogen atoms must be the same)

and the rest are algebra~ :)

set:
a = d ---(#alpha#)
b = e ---(#beta#)
b + c = 2e ---(#gamma#)
b + 2c = 3d + 2e ---(#delta#)

(#beta#)#->#(#gamma#)
b + c = 2e
e + c = 2e
c = e = b --- (#epsilon#)

(#epsilon#)#->#(#delta#)
b + 2c = 3d + 2e
b + 2b = 3d + 2b
3b = 3d + 2b
b = 3d = 3a --- (#varphi#)

#therefore#
when b = y

then
b = 3a
a = #1/3b#
a = #1/3y#

c = e = b = y

a = d
#1/3y# = d

so the whole equation is going to look like this:
#(1/3y)P + (y)NaOH + (y)H_2O# #-># #(1/3y)PH_3# + #(y)NaH_2PO_2#

multiply 3 both sides:
#(y)P + (3y)NaOH + (3y)H_2O# #-># #(y)PH_3# + #(3y)NaH_2PO_2#

devide y both sides:
#P + 3NaOH + 3H_2O# #-># #PH_3# + #3NaH_2PO_2#
TADA~~~

keep on learning my friend~ hope this helps you~