P+Naoh + H2O = PH3 + NaH2PO2 How to balance it?

1 Answer
May 4, 2018

P + 3NaOH + 3H_2O -> PH_3 + 3NaH_2PO_2

Explanation:

let's say:

(a)P + (b)NaOH + (c)H_2O -> (d)PH_3 + (e)NaH_2PO_2
we can know:
a = d (number of Phosphorus atoms must be the same)
b = e (number of Sodium atoms must be the same)
b + c = 2e (number of Oxygen atoms must be the same)
b + 2c = 3d + 2e (number of Hydrogen atoms must be the same)

and the rest are algebra~ :)

set:
a = d ---(alpha)
b = e ---(beta)
b + c = 2e ---(gamma)
b + 2c = 3d + 2e ---(delta)

(beta)->(gamma)
b + c = 2e
e + c = 2e
c = e = b --- (epsilon)

(epsilon)->(delta)
b + 2c = 3d + 2e
b + 2b = 3d + 2b
3b = 3d + 2b
b = 3d = 3a --- (varphi)

therefore
when b = y

then
b = 3a
a = 1/3b
a = 1/3y

c = e = b = y

a = d
1/3y = d

so the whole equation is going to look like this:
(1/3y)P + (y)NaOH + (y)H_2O -> (1/3y)PH_3 + (y)NaH_2PO_2

multiply 3 both sides:
(y)P + (3y)NaOH + (3y)H_2O -> (y)PH_3 + (3y)NaH_2PO_2

devide y both sides:
P + 3NaOH + 3H_2O -> PH_3 + 3NaH_2PO_2
TADA~~~

keep on learning my friend~ hope this helps you~