Assuming that the pressure should be in grams cms2 and not cms3 as in the question.
It is given that pv1.4=K and we are told that at time t, Pressure P=25 and at the same time t, Volume= 32, from this information we can work out the constant K.
Thus 25[321.4]=K, i.e K=3200
So, at time t , [pv1.4=3200].........[1], differentiating ....[1] implicitly with respect to pressure and time using the product rule, in this case [ ddt[pv]=vdpdt+pdvdt], where p and v and are both functions of t.
v1.4dpdt+p[1.4v0.4]dvdt=0.........[2]. We know dvdt at time t is 5 and we also know that at time t, p=25 and that the volume v=32 so we can substitute all these values into.....[2] and solve for dpdt
dpdt=−[[25][1.4][320.4]5321.4 This is the rate of change of pressure at time t. and is equal to -5.468cms2sec−1. Hope this helps.