How many π bonds are in a molecule of boron trifluoride?

1 Answer
Feb 4, 2014

The quick answer is, “There are no pi bonds in BF3, but the answer isn't quite that simple.

Explanation:

You can write four Lewis structures for BF3.

In one structure, the B atom has 3 single bonds to the F atoms and an incomplete octet.

The other three structures have double bonds to the F atoms.

wetche.cmbi.ru.nl

Most texts say that the double bond structures do not occur, because they put a positive charge on the F atom and result in a separation of charge.

Therefore, BF3 has no π bonds.

However, resonance theory says that when you can write more than one Lewis structure for a molecule, the actual structure is a resonance hybrid of them all.

The double bonded structures may be minor contributors, but they still contribute a little bit.

In that sense, the B-F bonds have some π character.

Furthermore, the length of the B-F bonds is shorter than expected for single bonds.

This is consistent with some degree of π bonding in BF3.

upload.wikimedia.org