If I understood the question correctly, the volume will be V=69.7L
Basically, you are dealing with the combustion of benzene, C6H6. Starting from the balanced reaction,
2C6H6+15O2→12CO2+6H2O
you can see that the benzene to oxygen ratio is 2:15; that is, for every 2 moles of benzene you need 15 moles of oxygen.
Your initial values are 0.5 moles for C6H6 and 3.75 moles for O2, which correspond to the balanced equation's ratio. This means that neither the benzene, nor the oxygen are limiting reactants.
So, for every 2 moles of C6H6 you will produce 12 moles of CO2 and 6 moles of H2O.
GIven that you have 0.5 moles to start with, you will end up with 3 moles of CO2 ( 1:6 ratio ) and 1.5 moles of H2O ( 1:3 ratio).
Now, using the ideal gas law PV=nRT and knowing that you have a total of 3+1.5=4.5 moles of gas produced, you get
V=nRTP=4.5⋅0.082⋅(105+273)2.0=69.7L