Question #a49bd

1 Answer
May 21, 2015

Your first reaction is actually a redox reaction (equilibrium, to be more precise) in which the silver cation, Ag+, oxidizes the iron (II) cations, Fe2+, to iron (III) cations, Fe3+.

In aqueous solution, the nitrate ions will act as spectator ions, so the net ionic equation will look like this

Fe3+(aq)+Ag+(aq)Fe3+(aq)+Ag(s)

The second one is a little tricky because you have two species that do not ionize in aqueous solution, phosphoric acid, H3PO4, and hydrogen sulfide, H2S.

The complete ionic equation looks like this

2H3PO4(aq)+6Na+(aq)+3S2(aq)3H2S(g)+6Na+(aq)+2PO34(aq)

If you eliminate the spectator ions, you'll get

2H3PO4(aq)+3S2(aq)3H2S(aq)+2PO34(aq)