Question #c8a2e

1 Answer
Nov 22, 2015

"0.9 atm"0.9 atm

Explanation:

The idea here is that you can use Dalton's law of partial pressures to help you find a relationship between the total pressure of gaseous mixture and the partial pressure of "B"B.

Now, the mole percent of a gas that's part of a gaseous mixture is simply the mole fraction of that gas multiplied by 100100.

color(blue)("mole%" = chi xx 100)" "mole%=χ×100 , where

chiχ - the mole fraction of the gas

This means that you can use the mole percent of gas "A"A to determine the mole fraction of this gas.

"mole %" = chi x 100 implies chi = "mole %"/100mole %=χx100χ=mole %100

Therefore, you have

chi_"A" = 10/100 = 0.1χA=10100=0.1

Since the mixture only contains two gases, "A"A and "B"B, it follows that their respective mole fractions must add up to give 11.

chi_"A" + chi_"B" = 1χA+χB=1

This means that the mole fraction of "B"B will be

chi_"B" = 1 - 0.1 = 0.9χB=10.1=0.9

Now, STP conditions are usually given as a pressure of "1 atm"1 atm and a temperature of 0^@"C"0C.

SIDE NOTE I say usually because the actual conditions for STP are a pressure of "100 kPa"100 kPa and a temperature of 0^@"C"0C.

Dalton's law of partial pressures tells you that the partial pressure of each component of a gaseous mixture is proportional to that component's mole fraction.

The total pressure of the mixture can thus be written as

P_"total" = overbrace(chi_"A" xx P_"total")^(color(red)("partial pressure of A")) + overbrace(chi_"B" xx P_"total")^(color(blue)("partial pressure of B"))

This means that the partial pressure of "B" will be equal to

P_"B" = chi_"B" xx P_"total"

P_"B" = 0.9 * "1 atm" = color(green)("0.9 atm")

You can read more on mole percent and mole fraction here:

http://socratic.org/questions/what-is-mole-percent