In X - Ray diffraction analysis the angle of the reflected beam for 1st order diffraction is sf(21.9^@). If the incident X - ray has a wavelength of 1.57color(white)(x)stackrel(@)"A"what is the separation of the crystal planes ?

1 Answer
Dec 12, 2015

2.10color(white)(x)stackrel(@)"A"

or 0.210color(white)(x)"nm"

Explanation:

This question is based on X - ray diffraction.

![chemistryviews.org](useruploads.socratic.orguseruploads.socratic.org)

The incident X - ray beams are reflected off the crystal layers as shown in the graphic.

After reflection the beams interfere with each other to produce a pattern which can be detected with a photographic plate.

If the X - rays are in phase constructive interference occurs:

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This produces a pattern on the plate enabling theta to be measured.

The condition for constructive interference to occur is that the path difference of the two beams must be a whole number of wavelengths.

From the graphic you can see that this path difference is dsintheta going in + dsintheta coming out.

Since this must be equal to a whole number of wavelengths lambda we can write:

nlambda=2dsintheta

Where n is an integer.

In this case n=1 so we can write:

d=(lambda)/(2sintheta)

:.d=(1.57)/(2xx0.373)=2.10color(white)(x)stackrel(@)"A"

The stackrel(@)("A")"ngstrom" unit is not strictly SI. This is equal to 0.210color(white)(x)"nm"