What is the oxidation state of the carbon atoms in acetylene?

1 Answer

Acetylene is a quite reduced form of carbon; the carbons each have a -II oxidation state.

Explanation:

Note that acetylene is neutral and while we can speak of the oxidation numbers of its atoms, we cannot speak of the molecule's oxidation state.

If we break up the C-HCH bonds we get 2xxH^+2×H+, and {C-=C}^(2-){CC}2 (carbon is more electronegative than hydrogen, so when you (for the purposes of assigning oxidation number) break this bond you put a formal +1+1 charge on hydrogen, and a formal -11 charge of carbon.

In fact, the acetylide unit {C-=C}^(2-){CC}2 occurs as calcium carbide, CaC_2CaC2, which is an important industrial feedstock.

More reduced forms of carbon include ethylene, H_2C=CH_2H2C=CH2, C^(-II)CII, and the methylene unit of a carbon , -CH_2CH2, C^(-II)CII. Oxidation state assignments are of course formalisms; they do not have real significance other than what we assign for them. When we break a C-CCC bond in such a process, we conceive we get 2xxC*2×C, i.e. neutral carbon radicals.