Question #62993

1 Answer
Feb 21, 2016

Yes, we can.

Explanation:

You're dealing with the hydrolisis of boron trichloride, BCl3.

This reaction will produce boric acid, which you'll see written both as H3BO3 and as B(OH)3, and hydrochloric acid, HCl.

The balanced chemical equation would indeed look like this

BCl3(aq]+3H2O(l]B(OH)3(aq]+3HCl(aq]

I'll try to explain what's going on here without going into too much detail. Mind you, this is a simplified version of what actually goes on, but it will give you an idea of how things work here.

The boron atom in boron trichloride, which is sp2 hybridized, has an empty 2p-orbital.

![http://www.tutorvista.com/content/chemistry/chemistry-iv/p-block-elements/http://reactivity-elements.php](https://useruploads.socratic.org/mX6pZJk4SCe06DaT1Fvr_boron-trihalides-structure.jpeg)

This means that it can act as a Lewis acid, i.e .accept a pair of electrons from the oxygen atom of a water molecule.

This will lead to the formation of an adduct, which is simply the result of the addition of two molecules.

Once this adduct, which can be represented as [H2OBCl3], is formed, a hydrogen atom located on the water molecule will jump off, leaving an OH group attached to the boron trichloride.

This will trigger the replacement of the BCl bonds with stronger BO bonds, resulting in the formation of boric acid, B(OH)3.

![npic.orst.edu)

As an interest follow-up, boric acid acts as an acid not because it donates protons, H+, but because it pulls another OH group from water to form the tetrahydroxyborate anion, [B(OH)4]

B(OH)3(aq]+H2O(l][B(OH)4(aq]]+H+(aq]