Why do we put a formal charge on nitrogen in ammonium cation?

1 Answer
Sep 5, 2016

NH_3(aq) + H_2O(l) rightleftharpoons NH_4^+ + HO^-NH3(aq)+H2O(l)NH+4+HO

Are we agreed that the above reaction is balanced with respect to mass and charge?

Explanation:

Ammonia is clearly a neutral molecule and its Lewis structure reflects this. Each hydrogen shares 1 electron from the N-HNH bond to balance its nuclear charge. The nitrogen atom has 2 inner core electrons, gets 3 electrons from the N-HNH bonds, and gets 2 electrons from the formal lone pair: 2+3+2=7e^-2+3+2=7e. These 7 electrons are precisely balanced by the 7 protons in the nitrogen nucleus (which nuclear charge must be there if it is a nitrogen atom).

Now when ammonia is quaternized, the nitrogen is conceived to have a half share only of the the electrons in the 4xxN-H4×NH bonds. So thus 44 electrons, + 22 inner core electrons, do not balance the +7+7 nuclear charge. Nitrogen, in ammonium ion is formally cationic. This is consistent with the stoichiometric equation.

Note that all of the N-HNH in ammonium are equivalent; the NH_4^+NH+4 cation is a tetrahedron. What hybridization would we assign the free base and the acid?