Which of the following solutions at equimolar solution would give the LOWEST pHpH?

(a)(a) "acetonitrile;"acetonitrile;
(b)(b) "calcium hydroxide;"calcium hydroxide;
(c)(c) "potasium hydroxide;"potasium hydroxide;
(d)(d) "hydroiodic acid;"hydroiodic acid;
(e)(e) "ammonia."ammonia.

1 Answer
Nov 1, 2016

Ca(OH)_2; KOH; NH_3; HC-=N; HICa(OH)2;KOH;NH3;HCN;HI

Explanation:

Hydrogen iodide is definitely the strongest acid in aqueous solution, and thus will give the lowest pHpH.

Hydrocyanic acid is a fairly weak Bronsted acid, but still the pHpH will be well below 77:

H-C-=N + H_2O rightleftharpoons H_3O^+ + N-=C^-HCN+H2OH3O++NC

Next cab off the rank is ammonia, which is a weak base in aqueous solution:

NH_3(aq) + H_2O rightleftharpoons NH_4^+ + HO^-NH3(aq)+H2ONH+4+HO

KOHKOH and Ca(OH)_2Ca(OH)2 are strong Bronsted bases, and will dissolve to give quantitative hydroxide ion. Since, you specified equal concentrations, calcium hydroxide delivers 2 equiv hydroxide anion, and will thus give the most basic solution, with the highest value of pHpH.