How do we represent the reduction of MnO_2MnO2 by chloride anion to give Mn^(2+)Mn2+ and chlorine gas?

1 Answer
Oct 30, 2016

This is a redox reaction: manganese is reduced......

MnO_2 +4H^+ + 2e^(-) rarr Mn^(2+) + 2H_2OMnO2+4H++2eMn2++2H2O (i)(i)

Explanation:

...........and chloride ion is oxidized.

Cl^(-) rarr 1/2Cl_2(g) + e^-Cl12Cl2(g)+e (ii)(ii)

(i) + (ii)xx2:(i)+(ii)×2: (we wish to remove electrons from the final redox equation.

MnO_2 +4H^+ + 2Cl^(-) rarr Mn^(2+) + Cl_2(g) + 2H_2OMnO2+4H++2ClMn2++Cl2(g)+2H2O