Identify the missing species and the radioactive decay process?
a)a) ""_(94)^(239) "Pu" + ""_0^1 "n" -> ""_(Z)^(A) + ""_(36)^(94) "Kr" + 2_(0)^(1) "n"23994Pu+10n→AZ+9436Kr+210n
b)b) ""_(92)^(233) + ""_(0)^(1) "n" -> ""_(51)^(133) "Sb" + ""_(Z)^(A)? + 3_(0)^(1) "n"23392+10n→13351Sb+AZ?+310n
c)c) ""_(56)^(128) "Ba" + ""_(-1)^(0) "e" -> ""_(Z)^(A) ? + gamma12856Ba+0−1e→AZ?+γ
d)d) ""_(Z)^(A) ? + ""_(-1)^(0) "e" -> ""_(35)^(81) "Br" + gammaAZ?+0−1e→8135Br+γ
1 Answer
For convenience, the original questions are copied down below.
When you set up the system of equations to solve this by asserting conservation of mass, just look across the top and across the bottom to get:
239 + 1 = A + 94 + 2(1)239+1=A+94+2(1)
94 + 0 = Z + 36 + 2(0)94+0=Z+36+2(0) Solving each one gives:
A = 239 + 1 - 94 - 2 = 144A=239+1−94−2=144
Z = 94 + 0 - 36 - 2(0) = 58Z=94+0−36−2(0)=58 So, your isotope has an atomic number of
5858 and a mass number of144144 , meaning that it is cerium-144,color(blue)(""_(58)^(144) "Ce")14458Ce .Nuclear fission is by definition absorbing a neutron and then splitting into two atoms and releasing a couple of neutrons.
Set up the system of equations:
233 + 1 = 133 + A + 3(1)233+1=133+A+3(1)
92 + 0 = 51 + Z + 3(0)92+0=51+Z+3(0) Solving these gives:
A = 233 + 1 - 133 - 3 = 98A=233+1−133−3=98
Z = 92 + 0 - 51 - 3(0) = 41Z=92+0−51−3(0)=41 Atomic number 41 is niobium, so we have
color(blue)(""_(41)^(98) "Nb")9841Nb . This is also nuclear fission for the same reason as inaa .
The missing product is
color(blue)(""_(55)^(128) "Cs")12855Cs .Since the isotope absorbs an electron to combine with a proton and form a neutron,
AA stays the same butZZ decreases by11 , so I'd call this electron capture.
This is just a variation on
ll . So, it's electron capture, and the missing reactant is""_(36)^(81) "Kr"8136Kr .