Identify the missing species and the radioactive decay process?

a)a) ""_(94)^(239) "Pu" + ""_0^1 "n" -> ""_(Z)^(A) + ""_(36)^(94) "Kr" + 2_(0)^(1) "n"23994Pu+10nAZ+9436Kr+210n

b)b) ""_(92)^(233) + ""_(0)^(1) "n" -> ""_(51)^(133) "Sb" + ""_(Z)^(A)? + 3_(0)^(1) "n"23392+10n13351Sb+AZ?+310n

c)c) ""_(56)^(128) "Ba" + ""_(-1)^(0) "e" -> ""_(Z)^(A) ? + gamma12856Ba+01eAZ?+γ

d)d) ""_(Z)^(A) ? + ""_(-1)^(0) "e" -> ""_(35)^(81) "Br" + gammaAZ?+01e8135Br+γ

1 Answer
Jan 7, 2017

For convenience, the original questions are copied down below.

a)a) ""_(94)^(239) "Pu" + ""_0^1 "n" -> ""_(Z)^(A) + ""_(36)^(94) "Kr" + 2_(0)^(1) "n"23994Pu+10nAZ+9436Kr+210n

When you set up the system of equations to solve this by asserting conservation of mass, just look across the top and across the bottom to get:

239 + 1 = A + 94 + 2(1)239+1=A+94+2(1)
94 + 0 = Z + 36 + 2(0)94+0=Z+36+2(0)

Solving each one gives:

A = 239 + 1 - 94 - 2 = 144A=239+1942=144
Z = 94 + 0 - 36 - 2(0) = 58Z=94+0362(0)=58

So, your isotope has an atomic number of 5858 and a mass number of 144144, meaning that it is cerium-144, color(blue)(""_(58)^(144) "Ce")14458Ce.

Nuclear fission is by definition absorbing a neutron and then splitting into two atoms and releasing a couple of neutrons.

b)b) ""_(92)^(233) + ""_(0)^(1) "n" -> ""_(51)^(133) "Sb" + ""_(Z)^(A)? + 3_(0)^(1) "n"23392+10n13351Sb+AZ?+310n

Set up the system of equations:

233 + 1 = 133 + A + 3(1)233+1=133+A+3(1)
92 + 0 = 51 + Z + 3(0)92+0=51+Z+3(0)

Solving these gives:

A = 233 + 1 - 133 - 3 = 98A=233+11333=98
Z = 92 + 0 - 51 - 3(0) = 41Z=92+0513(0)=41

Atomic number 41 is niobium, so we have color(blue)(""_(41)^(98) "Nb")9841Nb. This is also nuclear fission for the same reason as in aa.

c)c) ""_(56)^(128) "Ba" + ""_(-1)^(0) "e" -> ""_(Z)^(A) ? + gamma12856Ba+01eAZ?+γ

The missing product is color(blue)(""_(55)^(128) "Cs")12855Cs.

Since the isotope absorbs an electron to combine with a proton and form a neutron, AA stays the same but ZZ decreases by 11, so I'd call this electron capture.

d)d) ""_(Z)^(A) ? + ""_(-1)^(0) "e" -> ""_(35)^(81) "Br" + gammaAZ?+01e8135Br+γ

This is just a variation on ll. So, it's electron capture, and the missing reactant is ""_(36)^(81) "Kr"8136Kr.