Question #3b3c3
1 Answer
Explanation:
The idea here is that the boiling point of the solution will actually be higher than the boiling point of pure water, which means that the first thing to do here will be to figure out the boiling-point elevation, i.e. the difference between the boiling point of the solution and that of pure water.
Your tool of choice here will be the equation
#color(blue)(ul(color(black)(DeltaT = i * K_b * b)))#
Here
Water has an ebullioscopic constant equal to
#K_b = "0.512"""^@"C kg mol "^(-1)#
https://en.wikipedia.org/wiki/Ebullioscopic_constant
So, you know that your solution has a molality of
#b = "9.63 m" = "9.63 mol kg"^(-1)#
You also know that the solute is not ionic, which means that it does not dissociate in aqueous solution to produce ions.
Consequently, the van't Hoff fact, which tells you the ratio that exists between the number of moles of solute dissolved to make the solution and the number of moles of particles of solute produced in solution, will be equal to
#i = 1 -># you dissolve one mole of solute, you get one mole of particles of solute in solution
Therefore, you can say that the boiling-point elevation will be equal to
#DeltaT = 1 * "0.512" ""^@"C" color(red)(cancel(color(black)("kg")))color(red)(cancel(color(black)("mol"^(-1)))) * 9.63 color(red)(cancel(color(black)("mol"))) color(red)(cancel(color(black)("kg"^(-1))))#
#DeltaT = 4.93^@"C"#
Since this represents the increase in the boiling point of the solution when compared with the boiling point of the pure solvent,
#T_"b sol" = T_b^@ + DeltaT#
which gets you
#color(darkgreen)(ul(color(black)(T_"b sol" = 100^@"C" + 4.93^@"C" = 104.93^@"C")))#
The answer is rounded to two decimal places.