Why does a reaction with nitric acid produce nitrogen gas?

1 Answer
Mar 17, 2017

"HNO"_3 is also known as nitric acid. Concentrated nitric acid will produce nitrogen gas when reacted with MOST metal instead of hydrogen gas

Explanation:

color(red)("Why does HNO"_3" produce nitrogen gas instead of hydrogen gas?"
Concentrated nitric acid ("HNO"_3) is a strong oxidising agent. The hydrogen gas produced during its reaction with metal gets immediately oxidised to "H"_2"O", hence no hydrogen gas is produced. Instead, it evolves nitric oxides such as "NO"_2", NO" etc.

Take color(blue)("copper") for example,

"Cu(s) + 4HNO"_3"(aq)⟶Cu(NO"_3)_2"(aq) + 2NO"_2"(g) + 2H"_2"O(l)"

color(red)("What metals react with HNO3 to form hydrogen gas?"

"HNO"_3 (about 1% concentrated) doesn’t oxidise Mg and Mn a lot and so it reacts with them as you would expect an acid to react, releasing hydrogen.

Take color(blue)("magnesium") for example,

"Mg"+"2HNO"_3"⟶Mg(NO"_3)_2""+"H"_2"