If a block of material is heated, it will expand in all directions.
So in a block of #1mxx1mxx1m# with a linear coefficient of #alpha# the volume increases from #1m^3# to #(1+alpha)^3m^3# per degree.
Since #alpha# is very small (in the region of #10^(-5)//K#), we can say that #(1+alpha)^3~~1+3alpha# with sufficient precision.
So the co-efficient of volumetric expansion: #gamma~~3alpha#
Note:
#(1+alpha)^3=1+3alpha+3alpha^2+alpha^3# (Pascal)
Since #alpha# is very small (#~~10^-5#), #alpha^2# will be in the region of #10^(-10)# and #alpha^3~~10^(-15)#.
These can be neglected, hece #(1+alpha)^3~~1+3alpha#
Note 2:
Of course, with liquids you can only measure volume expansion.