Why do some people call (H3C)4C neopentane instead of dimethyl propane?

1 Answer
Apr 14, 2017

Because some people (including me!) are a bit old-fashioned.........

Explanation:

(H3C)4C, has a molecular formula of C5H12, i.e. it is an isomer of pentane. We could call this dimethylpropane (am I correct in omitting the numbers, i.e. NOT stating 2,2-dimethylpropane?), but I think it is easier to call this neopentane. Such so-called trivial names are recognized by most chemists, and most schemes of nomenclature.

The neopentyl group is C5H11, e.g. neopentyl lithium Li+CH2C(CH3)3; likewise the neosilyl group is (H3C)3SiCH2, i.e. C4SiH11..............