Question #c5cb2

1 Answer
Apr 16, 2017

By the problem the following gaseous reaction is occuring in closed, rigid vessel at constant temperature.

W(g)+X(g)Y(g)+Z(g)

The stoichiometric ratio of number of moles of reactants and prducts is

W(g):X(g):Y(g):Z(g)=1:1:1:1

The volume and temperature remaining constant the partial pressures of the component gases are proportional to their number of moles.

The initial partial pressures of W(g)andX(g) are 1.2 atm and 1.6 atm respectively.
And the initial partial pressures of Y(g)andZ(g) are 0 atm.

If the partial pressure of W(g) is decreased to 1atm then the 0.2atm decrease is due to its taking part in the reaction.
So the decrease in pressure of X(g) will also be 0.2 atm.

But pressures of each of Y(g)andZ(g) will be inreased to 0.2atm as the interacting mole ratio is 1:1:1:1