Question #ee4f4

1 Answer
Jul 8, 2017

"0.407 nm"0.407 nm

Explanation:

The idea here is that you need to use the configuration of a face-centered cubic unit cell to find a relationship between the length of the cell, which is usually labeled aa, and the radius of an atom of gold, which is usually labeled rr.

So, a face-centered cubic unit cell looks like this

![https://classconnection.s3.amazonaws.com/38/flashcards/512038/png/fcc1316360426857png](useruploads.socratic.orguseruploads.socratic.org)

Now, you should know that the diagonal of a square is equal to

"diagonal" = "side" xx sqrt(2)diagonal=side×2

In this case, the diagonal of a face has a length of

"diagonal" = r + 2r + r = 4rdiagonal=r+2r+r=4r

Here rr represents the radius of the two quarter of an atom that occupy the two corners of the face and 2r2r represents the diameter of the atom that occupies the middle of the face.

![www.chemteam.infowww.chemteam.info)

This means that the length of the side of the unit cell

"side" = "diagonal"/sqrt(2)side=diagonal2

will be equal to

a = (4r)/sqrt(2) = (4r sqrt(2))/2 = 2sqrt(2) * ra=4r2=4r22=22r

Plug in your value to find

a = 2 sqrt(2) * "0.144 nm" = color(darkgreen)(ul(color(black)("0.407 nm")))

The answer is rounded to three sig figs.