How do we represent the formation of Fe3O4 by the oxidation of iron metal in basic conditions?

1 Answer
Jul 11, 2017

3Fe(s)+8H2OFe2++2Fe3++4H2(g)+8HO

Explanation:

If you got Fe3O4, this is mixed valence oxide of iron ......it occurs as the mineral magnetite, which we could formulate as FeOFe2O3Fe3O4.......

And so metallic iron is oxidized to Fe2++2×Fe3+............

3Fe(s)Fe2++2Fe3++8e (i)

But something must be correspondingly reduced.....and here it is the protium ion in water........

H2O+e12H2(g)+HO (ii)

And so I take (i)+8×(ii) to gives...........

3Fe(s)+8H2OFe2++2Fe3++4H2(g)+8HO

Charge and mass are balanced as is required...........