At NTPNTP, for a DIATOMIC gas, how many atoms constitute a 5.6*L5.6L volume?

2 Answers
Jul 15, 2017

2.80xx10^232.80×1023 "atoms"atoms

Explanation:

We're asked to calculate the number of atoms in 5.65.6 "L"L of a diatomic gas at normal temperature and pressure (NTP).

To do this, we can use the ideal-gas equation:

PV = nRTPV=nRT

where

  • PP is the pressure exerted by the gas, in units of "atm"atm (at NTP, the pressure is defined as 11 "atm"atm

  • VV is the volume occupied by the gas, in units of "L"L (given as 5.65.6 "L"L)

  • nn is the number of moles of gas present (we'll need to find this)

  • RR is the universal gas constant, equal to 0.082057("L"·"atm")/("mol"·"K")0.082057LatmmolK

  • TT is the absolute temperature of the gas, in units of "K"K (the temperature at NTP is defined as 20^"o""C"20oC, which is

20^"o""C" + 273.15 = 293.1520oC+273.15=293.15 "K"K)

Plugging in known values, and solving for the quantity, nn, we have

n = (PV)/(RT) = ((1cancel("atm"))(5.6cancel("L")))/((0.082057(cancel("L")·cancel("atm"))/("mol"·cancel("K")))(293.15cancel("K"))) = color(red)(0.233 color(red)("mol gas"

Using Avogadro's number, we can convert from moles of gas to molecules:

color(red)(0.233)cancel(color(red)("mol gas"))((6.022xx10^23color(white)(l)"molecules gas")/(1cancel("mol gas")))

= 1.40xx10^23 "molecules gas"

We're given that the gas is diatomic, meaning there are two atoms per molecule, so the total number of atoms is

1.40xx10^23cancel("molecules gas")((2color(white)(l)"atoms gas")/(1cancel("molecule gas")))

= color(blue)(2.80xx10^23 color(blue)("atoms"

Jul 15, 2017

Approx. 0.466xxN_A

Explanation:

So far as I know "NTP" specifies conditions of 1*atm, 293.15*K, and with this we solve for n in the Ideal Gas Equation......

n=(PV)/(RT)=(1*atmxx5.6*L)/(0.0821*(L*atm)/(K*mol)xx293.15*K)=0.233*mol.....

But we are not finished there. We were asked for the NUMBER of ATOMS of X_2 (and in fact most elemental gases are binuclear, certainly the interesting ones), and so we multiply this figure appropriately........

"Number of atoms"=2xx0.233*molxx6.022xx10^23*mol^-1 ~=1/2N_A.

Note that looking at last year's exam paper they quoted both "NTP" and "STP" as supplementary material on the paper.......