Given an organic formula, how do you assess the number of double bonds in an organic molecule?

1 Answer
Jul 20, 2017

We assess the [degree of unsaturation.](https://socratic.org/questions/how-are-cycloalkanes-different-from-aromatic-compounds)

Explanation:

An unsaturated organic compound has formula C_nH_(2n+2). Each degree of unsaturation REDUCES the hydrogen count by 2, and corresponds to a RING JUNCTION or an olefinic bond. When oxygen appears in the formula, we assess the degree of unsaturation directly (and of course a degree of unsaturation could correspond to C=O). Halogens count for 1*H; we subtract NH from the formula if nitrogen is present.

And thus HC-=CH has 2 degrees of unsaturation, it is an alkyne.

And H_3C-CH_3 has 0 degrees of unsaturation.....an alkane.

And H_2C=CH_2 has 1 degree of unsaturation.....an olefin, or alkene.

And H_3C-CH_2NH_2-=C_2H_6...no degrees of unsaturation.

And C_3H_6 has 1 degrees of unsaturation.....an alkene, i.e. H_3C-CH-CH_2 OR "cyclopropane".

And C_3H_8 has 0 degrees of unsaturation.....an alkane.