Question #3ed00

1 Answer
Aug 8, 2017

The relative atomic mass of the element is 48.

Explanation:

The idea here is that the vapor density of the chloride will help you determine its molar mass.

As you know, the vapor density of a gas is defined as the ratio that exists between the molar mass of the gas and the molar mass of hydrogen gas, "H"_2.

In your case, you have

"VD" = "molar mass chloride"/"molar mass H"_2 = 59.5

To make the calculations easier, you can use the approximation

"molar mass H"_2 ~~ "2 g mol"^(-1)

This means that you have

"molar mass chloride" = 59.5 * "2 g mol"^(-1)

"molar mass chloride" = "119 g mol"^(-1)

Now, you know that the equivalent mass of the metal is equal to "24 g". In your case, the equivalent mass of the metal, which is essentially the mass of 1 equivalent of metal, tells you the mass of metal that combines directly with "35.5 g" of chlorine, "Cl".

So if "24 g" of the metal combine with "35.5 g" of chlorine, it follows that you have

"24 g metal + 35.5 g Cl = 59.5 g chloride"

"24 g metal + 35.5 g Cl = 59.5 g chloride"
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"48 g metal + 71 g Cl = 119 g chloride"

This means that "48 g" of metal combine with "71 g" of chlorine to form "119 g" of metal chloride, which tells you that the mass of 1 mole of metal, which is equal to 2 equivalents of metal, is equal to

"molar mass metal = 48 g mol"^(-1)

The relative atomic mass of the metal will thus be

A_r = (48 color(red)(cancel(color(black)("g mol"^(-1)))))/(1color(red)(cancel(color(black)("g mol"^(-1))))) = 48