What volume of dioxygen gas would be generated by complete decomposition of a 10g mass of KClO3, under a pressure of 750mmHg?

1 Answer
Sep 3, 2017

Well, we need a stoichiometric equation......and I get under 2L.

Explanation:

KClO3MnO2−−32O2(g)+KCl

Some Mn(IV) salt is usually added to catalyze the reaction.

Moles of potassium chlorate=10g122.55gmol1

=0.0816mol

And thus we gets 32×0.0816mol=0.122mol dioxygen gas.

And then we simply solve the Ideal Gas equation.....

V=nRTP=0.0816mol×0.0821LatmKmol×291K750mmHg760mmHgatm1

=??L

Note the pressure measurement. A mercury column is a VERY convenient means to measure gas pressure in that we know that 1atm will support a column of mercury that is 760mm high. These days mercury has all but disappeared from laboratories because of perceived safety concerns. (I keep my manometers under lock and key, away from nosy safety inspectors).