A chemistry has 14.5 g of Al and 7.5 g of O_2O2. What would the excess be for the following reaction: 4Al + 3O_2 -> 2Al_2O_34Al+3O22Al2O3?

1 Answer
Sep 8, 2017

Al is in limiting
O_2O2 is in excess

Explanation:

To check excess and limiting reactants, the number of moles has to be found, and then divided by the coefficient.
For the sake of shortening the equations, let us say that:

n="number of moles"n=number of moles
m="mass"m=mass
M="molar mass"M=molar mass

To find the number of moles, we need to use the formula:

n=m/Mn=mM

The mass is given in the question:
m_"Al"=14.5gmAl=14.5g
m_"Oxygen gas"=7.5gmOxygen gas=7.5g

Molar mass of Al and Oxygen can be found in periodic table,
M_"Al"≈27g/molMAl27gmol
M_"Oxygen gas"= 2*M_"Oxygen atom"≈2* 16=32 "g/mol"MOxygen gas=2MOxygen atom216=32g/mol
(since oxygen gas (O_2O2) has two atoms of Oxygen (O))

Now putting these values for the number of moles's formula:
For Al

n=m/M=14.5/27=0.537 molsn=mM=14.527=0.537mols

For O_2O2

n=7.5/32=0.234 molsn=7.532=0.234mols

After getting the number of moles, we just still have to divide them by their respective coefficients, and comparing them.

For Al

n/4=0.537/4=0.134n4=0.5374=0.134

For O_2O2

n/2=0.234/2=0.17n2=0.2342=0.17

The reactant with the bigger value will be in excess and the reactant with the smaller value will be in limiting

"the value of Al (0.134)"< "the value of O_2 (0.17)"the value of Al (0.134)<the value of O_2 (0.17)

Therefore, Al is in limiting (there is less of it and thus it is limiting the reaction) and O_2O2 is in excess.

Hope that this will help. :)