At standard pressure, CH4 boils at 112 K and H2O boils at 373 K. What accounts for the higher boiling point of H2O at standard pressure?

1 Answer
Dec 31, 2016

Intermolecular force differentiates..........

Explanation:

Between water molecules, hydrogen bonding operates, which is a potent intermolecular force. The HO bond is quite polar, i.e. δ+HOδHδ+, and the dipoles can align. No such intermolecular force operates between methane molecules, (because the CH bond is reasonably non-polar), and the boiling point of methane is substantially reduced with respect to water.