How can you model half life decay?

1 Answer
Jul 3, 2016

The equation would be:

[A]=12t/t1/2[A]0

Read on to know what it means.


Just focus on the main principle:

The upcoming concentration of reactant A after half-life time t1/2 becomes half of the current concentration.

So, if we define the current concentration as [A]n and the upcoming concentration as [A]n+1, then...

[A]n+1=12[A]n (1)

We call the (1) the recursive half-life decay equation for one half-life occurrence, i.e. when t1/2 has passed by only once. This isn't very useful though, because half-lives can range from very slow (thousands of years) to very fast (milliseconds!).

Let's go through another half-life, until we've gone through n half-lives. For this, we rewrite [A]n as [A]0 (the initial concentration), and [A]n+1 as [A] (the upcoming concentration).

Notice how [A]0 will always be the same, but [A] will keep changing over time.

[A]=(12)(12)(12)[A]0

=(12)n[A]0

[A]=12n[A]0 (2)

Now we have (2), the equation for any number of half-life decays... once we know how many half-lives passed by.

However, (2) can be made more convenient since we know that each half-life takes t1/2 time to occur. When n half-lives occur, each one taking t1/2 to occur, it must occur over a set amount of time t. So:

nt1/2=t (3)

That means n=tt1/2, which is saying that we can divide the total time passed during the process by the time it takes to lose half of A again to get the number of half-lives that passed by.

Therefore:

[A]=12t/t1/2[A]0 (4)

So, we can use (4) to determine half-lives of any typical radioactive element for which we know t, the time passed during the half-life decay(s) AND:

  • [A]0, the initial concentration, and [A], the upcoming concentration, OR
  • [A][A]0, the fraction of the element left after time t passes.