How do structural isomers arise?

1 Answer
Jan 22, 2017

By the ability of a given formula to give rise to distinct structures.....

Explanation:

Structural isomerism arises from differing connectivity. An organic formula of C4H10 can give rise to two structural isomers: n-butane, H3CCH2CH2CH3; and methylpropane or isobutane, H3CCH(CH3)CH3.

As the organic formula becomes larger, the number of possible isomers necessarily increase. C5H12 can generate 3 structural isomers. And hexane, C6H14 can generate 5 structural isomers. And so on...........the larger alkanes can generate many structural isomers.

The possibility of isomerism demands the need for an efficient and recognized system of identification that can name a given structural isomer straightforwardly and unambiguously. This is why educators go to such lengths to introduce nomenclature schemes.