Recall that y = tanx can be written as y = sinx/cosx. Then there will be asymptotes whenever cosx = 0, since we cannot have the denominator equal 0 without making the function undefined in the real number system.
Similarly, f(x) = tan2x can be rewritten as f(x) = (sin2x)/(cos2x). We need to find the values of x that make cos2x= 0.
cos2x= 0
2x = arccos(0)
2x = pi/2, (3pi)/2
x = pi/4 and (3pi)/4
Don't forget to add the periodicity. The function y = cos2x has a period of pi, so there will be asymptotes in tan(2x) whenever x= pi/4 + pin or x = (3pi)/4 + pin, where n is an integer.
Hopefully this helps!