How do you write a balanced chemical equation for the removal of lead (II) nitrate using hydrogen sulfide? What is the precipitate formed?

1 Answer
Mar 18, 2016

The reaction forms lead(II) sulfide.

Explanation:

Lead(II) nitrate, "Pb"("NO"_3)_2Pb(NO3)2, is a soluble ionic compound that dissociates completely in aqueous solution to form lead(II) cations, "Pb"^(2+)Pb2+, and nitrate anions, "NO"_3^(-)NO3.

"Pb"("NO"_3)_text(2(aq]) -> "Pb"_text((aq])^(2+) + 2"NO"_text(3(aq])^(-)Pb(NO3)2(aq]Pb2+(aq]+2NO3(aq]

In order to precipitate the lead(II) cations, hydrogen sulfide, "H"_2"S"H2S, is bubbled through the solution.

This will result in the formation of lead(II) sulfide, "PbS"PbS, an insoluble ionic compound that will precipitate out of solution.

The complete ionic equation will look like this

"Pb"_text((aq])^(2+) + 2"NO"_text(3(aq])^(-) + "H"_2"S"_text((aq]) -> "PbS"_text((s]) darr + 2"H"_text((aq])^(+) + 2"NO"_text(3(aq])^(-)Pb2+(aq]+2NO3(aq]+H2S(aq]PbS(s]+2H+(aq]+2NO3(aq]

To get the net ionic equation, remove the spectator ions, i.e. the ions that exist on both sides of the equation

"Pb"_text((aq])^(2+) + color(red)(cancel(color(black)(2"NO"_text(3(aq])^(-)))) + "H"_2"S"_text((aq]) -> "PbS"_text((s]) darr + 2"H"_text((aq])^(+) + color(red)(cancel(color(black)(2"NO"_text(3(aq])^(-))))

This will get you

"Pb"_text((aq])^(2+) + "H"_2"S"_text((aq]) -> "PbS"_text((s]) darr + 2"H"_text((aq])^(+)

The color of the solution will change from colorless to black once the lead(II) sulfide precipitates out of solution.

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