How do you write the formula of an ionic compound?

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1 Answer
Jun 6, 2014

What you want to do is make the compound neutral.

Let's take the following example:

#Na^(+)# + #SO_4^(2-)#

We need to balance the charges, the easiest way to balance this charge is by looking at the overall charge of the ions involved. The #Na# ion has a #+1# charge and the #SO_4# ion has a #-2# charge. In order to give balance, we must have two Na ions to give an overall #+2# with regards to Na: this, thus, neutralises the compound. Therefore, the formula is:

#Na_2SO_4#

If you're asked to balance an ionic compound such as Iron(III) Hydroxide, write down the formula. We know that Fe (Iron) has a #3+# charge and the hydroxide ion (OH) has a #1-# charge - as a result, the compounds in their individualised forms are:

#Fe^(3+)# and #OH^(-)#

In order to balance this, we need to add brackets around the hydroxide ion to give:

#Fe(OH)_3#

This balances the charges and, thus, an accurate ionic formula has been given.