How does partial pressure affect delta G?

1 Answer
Sep 26, 2015

DeltaG=DeltaG^@+RTln(((P_(NH_3))^2)/(P_(N_2)*(P_(H_2))^3))

Explanation:

The relationship between DeltaG and pressure is: DeltaG=DeltaG^@+RTlnQ

Where Q is the reaction quotient, that in case of a reaction involving gaseous reactants and products, pressure could be used.

For example: N_2(g) + 3H_2(g) -> 2NH_3(g)

The reaction quotient is: Q=((P_(NH_3))^2)/(P_(N_2)*(P_(H_2))^3)

Therefore, DeltaG=DeltaG^@+RTln(((P_(NH_3))^2)/(P_(N_2)*(P_(H_2))^3))

I recommend this video that explains this concept in details: