How many equivalent hydrogens does ethanol have?

1 Answer
Aug 19, 2015

Ethanol has three sets of equivalent hydrogens.

Explanation:

The structure of ethanol is

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The molecule contains six #"H"# atoms. Some of them are different from each other.

For example, there are three equivalent #"H"# atoms on the #"CH"_3# group.

They are different from the hydrogens on the #"CH"_2# group.

And the #"H"# atom on the oxygen is different from all the others.

One way to check whether certain #"H"# atoms are equivalent is to replace each #"H"# atom with a group like #"Cl"# and see if you generate the same compound.

Replacing any #"H"# atom in the #"CH"_3# group gives #"ClCH"_2"CH"_2"OH"#.

Replacing any #"H"# atom in the #"CH"_2# group gives #"CH"_3"CHClOH"#.

Replacing the #"H"# atom on the #"O"# gives #"CH"_3"CH"_2"OCl"#.

Here is the NMR spectrum of ethanol.

upload.wikimedia.org
(from en.wikipedia.org)

The three blue, the two green, and the single red hydrogen make up three different sets of equivalent hydrogens.