How many equivalent hydrogens does ethanol have?

1 Answer
Aug 19, 2015

Ethanol has three sets of equivalent hydrogens.

Explanation:

The structure of ethanol is

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The molecule contains six "H" atoms. Some of them are different from each other.

For example, there are three equivalent "H" atoms on the "CH"_3 group.

They are different from the hydrogens on the "CH"_2 group.

And the "H" atom on the oxygen is different from all the others.

One way to check whether certain "H" atoms are equivalent is to replace each "H" atom with a group like "Cl" and see if you generate the same compound.

Replacing any "H" atom in the "CH"_3 group gives "ClCH"_2"CH"_2"OH".

Replacing any "H" atom in the "CH"_2 group gives "CH"_3"CHClOH".

Replacing the "H" atom on the "O" gives "CH"_3"CH"_2"OCl".

Here is the NMR spectrum of ethanol.

upload.wikimedia.org
(from en.wikipedia.org)

The three blue, the two green, and the single red hydrogen make up three different sets of equivalent hydrogens.