How many isomers are possible for [Cr(NO_2)(NH_3)_5]Cl_2?

1 Answer
Dec 16, 2016

A couple, but there is of course a catch.......

Explanation:

For the complex ion [Cr(NO_2)(NH_3)_5]^(2+), only the one isomer would be available but for the ambident nature of the ligand, NO_2^-.

"Nitro-nitrito" isomerism can occur, depending on whether the ligand is "N-bound, nitro" or "O-bound, nitrito"; and thus 2 isomers are possible. The NO_2^- ligand can also bind in a chelate fashion, but I doubt it is doing so in a co-ordinatively saturated Cr(III+) complex.