We use the Ideal Gas Equation, with R=0.0821*L*atm*K^-1*mol^-1.
And thus n=(PV)/(RT)=(3.48*cancel(atm)xx1*cancel(m^3)xx10^3*cancelL*cancel(m^-3))/(0.0821*cancel(L*atm)*cancel(K^-1)*mol^-1xx295*cancelK)
=143.7*mol (note that the answer has units 1/(mol^-1)=1/(1/(mol))=mol "as required"
And we convert this molar quantity into a mass:
143.7*cancel(mol)xx32.00*cancel(g*mol^-1)xx10^-3*kg*cancel(g^-1)
=4.60*kg.
Please review my arithmetic. There are no money-back guarantees.
Note that 1*m^3 is a very large volume, and is equal to 1000*L. Chemists tend to deal with "litres" and mL and cm^3 (1*mL-=1*cm^3-=10^-3*L-=10^-6*m^3). Of course all the measurements should be equivalent dimensionally, but it is so easy to divide instead of multiply and vice versa.