Use the ideal gas law. The formula is PV=nRT, where P is pressure, V is volume, n is moles, R is the gas constant, and T is the Kelvin temperature.
Given/Known
P="750 mmHg"="750 Torr"
V=890cancel"mL"xx(1"L")/(1000cancel"mL")="0.89 L"
R="62.363577 L Torr K"^(-1) "mol"^(-1)
https://en.m.wikipedia.org/wiki/Gas_constant
T="21"^@"C"+273.15"=294 K"
Unknown
n
Solution
Rearrange the formula to isolate n. Substitute the given/known values into the formula and solve.
PV=nRT
n=(PV)/(RT)
n=(750cancel"Torr" * 0.89cancel"L")/((62.363577 cancel"L" cancel"Torr" cancel"K"^(-1)" mol"^(-1))xx(294cancel"K"))="0.036 mol" rounded to two significant figures