How would you balance PCl5 + H2O -->H3PO4 + HCl?

1 Answer
Oct 25, 2015

PCl_5 + 4H_2O = H_3PO_4 + 5HCl

Explanation:

Just create a tally sheet for all the elements involve.

PCl_5 + H_2O = H_3PO_4 + HCl

Left side:
P = 1
Cl = 5
H = 2
O = 1

Right side:
P = 1
Cl = 1
H = 3 + 1 (DO NOT ADD IT UP YET)
O = 4

Start balancing the easiest element, in this case, the Cl.

Left side:
P = 1
Cl = 5
H = 2
O = 1

since HCl is a substance, you need to also multiply its H by 5.

Right side:
P = 1
Cl = 1 x 5 = 5
H = 3 + (1 x 5) = 8
O = 4

PCl_5 + H_2O = H_3PO_4 + 5HCl

Now the H atom on the left side is not balance with the right side, we have to multiply the H on the left side by 4.

Left side:
P = 1
Cl = 5
H = 2 x 4 = 8
O = 1 x 4 = 4

Again, since H_2O is a substance, you also need to multiply its O by 4.

Right side:
P = 1
Cl = 1 x 5 = 5
H = 3 + (1 x 5) = 8
O = 4

PCl_5 + 4H_2O = H_3PO_4 + 5HCl

The equation is now balanced.