How would you determine the molecular formula of NPCl_2 (347.64 g/mol)?

How would you determine the molecular formula of NPCl_2 (347.64 g/(mol))?

1 Answer
Nov 7, 2015

I presume you have quoted the empirical formula in PNCl_2. The molecular formula is ALWAYS a multiple of the empirical formula

Explanation:

Given that (EF)_n = MF, all we have to do is to use atomic masses and solve for n.

So 347.64*g*mol^(-1) = nxx(30.9747+14.01+2xx35.45)*g*mol^-1.

And 347.64*g*mol^(-1) = n(115.88)*g*mol^(-1)

n = ?? And molecular formula = (PNCl_2)xxn = P_31N_5Cl_102?

Note that sometimes (but not here). the empirical formula is the same as the molecular formula.