In the sulfate ion (SO24), how many electrons are available for bonding?

1 Answer
Dec 3, 2016

There are 5×6+2=32 valence electrons, distributed around 5 centres. 12 electrons are formally involved in bonding.

Explanation:

A typical valence bond representation of the sulfate dianion is as O2S(=O)2 (this derives from the parent sulfuric acid, (HO)2S(=O)2). Around the sulfur centre there are 6 valence electrons, participating in single or multiple sulfur-oxygen bonds.

What is the geometry around sulfur?

A representation of (HO)2S2+(O)2 is also feasible, but the sulfur oxygen double bonds are usually depicted.

Note that the electron count was simply obtained by the operation 5×6+2=32 valence electrons. Why did I add an additional 2 electrons?