In this reaction, 4.58L of O_2 were formed at 745 mmHg and 308K. How many grams of Ag_2O decomposed? 2Ag_2O_((s)) -> 4Ag_((s)) + O_(2(g))

1 Answer
May 22, 2015

Your reaction required the decomposition of 82.5 g of silver oxide.

Start with the balanced chemical equation

color(red)(2)Ag_2O_((s)) -> 4Ag_((s)) + O_(2(g))

Notice that you have a color(red)(2):1 mole ratio between silver oxide and oxygen gas. This tells you that, regardless of how many moles of oxygen the reaction produced, two times more moles of silver oxide underwent decomposition.

Use the ideal gas law equation to determine how many moles of oxygen were produced

PV = nRT => n = (PV)/(RT)

n_(O_2) = (745/760cancel("atm") * 4.58cancel("L"))/(0.082(cancel("atm") * cancel("L"))/("mol" * cancel("K")) * 308cancel("K")) = "0.178 moles" O_2

Use the aforementioned mole ratio to determine how many moles of silver oxide reacted

0.178cancel("moles"O_2) * (color(red)(2)" moles"Ag_2O)/(1cancel("mole"O_2)) = "0.356 moles" Ag_2O

Now use silver oxide's molar mass to determine how many grams would contain this many moles

0.356cancel("g") * ("1 mole" Ag_2O)/(231.74cancel("g")) = color(green)("82.5 g")