Solubility of Mg(OH)_2Mg(OH)2 is 1.61.6 x 10^-410−4 "mol/L"mol/L at 298298 KK. What is its solubility product?
1 Answer
Explanation:
Magnesium hydroxide,
Magnesium hydroxide dissociates only partially to form magnesium cations,
"Mg"("OH")_text(2(s]) rightleftharpoons "Mg"_text((aq])^(2+) + color(red)(2)"OH"_text((aq])^(-)Mg(OH)2(s]⇌Mg2+(aq]+2OH−(aq]
For an insoluble compound, its molar solubility tells you how many moles of the compound can be dissolved per liter of aqueous solution before reaching saturation.
In your case, a molar solubility of
s = 1.6 * 10^(-4)s=1.6⋅10−4
means that you can only dissolve
Take a look at the dissociation equilibrium. Notice that every mole of magnesium hydroxide that dissociates produces
This tells you that if you successfully dissolve
n_(Mg^(2+)) = 1 xx 1.6 * 10^(-4) = 1.6 * 10^(-4)"moles Mg"^(2+)nMg2+=1×1.6⋅10−4=1.6⋅10−4moles Mg2+
and
n_(OH^(-)) = color(red)(2) xx 1.6 * 10^(-4) = 3.2 * 10^(-4)"moles"nOH−=2×1.6⋅10−4=3.2⋅10−4moles
Since we're working with one liter of solution, you can cay that
["Mg"^(2+)] = 1.6 * 10^(-4)"M"[Mg2+]=1.6⋅10−4M
["OH"^(-)] = 3.2 * 10^(-4)"M"[OH−]=3.2⋅10−4M
By definition, the solubility product constant,
K_(sp) = ["Mg"^(2+)] * ["OH"^(-)]^color(red)(2)Ksp=[Mg2+]⋅[OH−]2
Plug in these values to get
K_(sp) = 1.6 * 10^(-4) * (3.2 * 10^(-4))^color(red)(2)Ksp=1.6⋅10−4⋅(3.2⋅10−4)2
K_(sp) = color(green)(1.6 * 10^(-11)) ->Ksp=1.6⋅10−11→ rounded to two sig figs
The listed value for magnesium hydroxide's solubility product is
http://www.wiredchemist.com/chemistry/data/solubility-product-constants