Solubility of Mg(OH)_2Mg(OH)2 is 1.61.6 x 10^-4104 "mol/L"mol/L at 298298 KK. What is its solubility product?

1 Answer
Jan 31, 2016

1.6 * 10^(-11)1.61011

Explanation:

Magnesium hydroxide, "Mg"("OH")_2Mg(OH)2, is considered Insoluble in aqueous solution, which implies that the ions it forms will be in equilibrium with the solid.

Magnesium hydroxide dissociates only partially to form magnesium cations, "Mg"^(2+)Mg2+, and hydroxide anions, "OH"^(-)OH

"Mg"("OH")_text(2(s]) rightleftharpoons "Mg"_text((aq])^(2+) + color(red)(2)"OH"_text((aq])^(-)Mg(OH)2(s]Mg2+(aq]+2OH(aq]

For an insoluble compound, its molar solubility tells you how many moles of the compound can be dissolved per liter of aqueous solution before reaching saturation.

In your case, a molar solubility of

s = 1.6 * 10^(-4)s=1.6104

means that you can only dissolve 1.6 * 10^(-4)1.6104 moles of magnesium in a liter of water at that temperature.

Take a look at the dissociation equilibrium. Notice that every mole of magnesium hydroxide that dissociates produces 11 mole of magnesium cations and color(red)(2)2 moles of hydroxide anions.

This tells you that if you successfully dissolve 1.6 * 10^(-4)1.6104 moles of magnesium hydroxide in one liter of solution, number of moles of each ion will be

n_(Mg^(2+)) = 1 xx 1.6 * 10^(-4) = 1.6 * 10^(-4)"moles Mg"^(2+)nMg2+=1×1.6104=1.6104moles Mg2+

and

n_(OH^(-)) = color(red)(2) xx 1.6 * 10^(-4) = 3.2 * 10^(-4)"moles"nOH=2×1.6104=3.2104moles

Since we're working with one liter of solution, you can cay that

["Mg"^(2+)] = 1.6 * 10^(-4)"M"[Mg2+]=1.6104M

["OH"^(-)] = 3.2 * 10^(-4)"M"[OH]=3.2104M

By definition, the solubility product constant, K_(sp)Ksp, will be equal to

K_(sp) = ["Mg"^(2+)] * ["OH"^(-)]^color(red)(2)Ksp=[Mg2+][OH]2

Plug in these values to get

K_(sp) = 1.6 * 10^(-4) * (3.2 * 10^(-4))^color(red)(2)Ksp=1.6104(3.2104)2

K_(sp) = color(green)(1.6 * 10^(-11)) ->Ksp=1.61011 rounded to two sig figs

The listed value for magnesium hydroxide's solubility product is 1.6 * 10^(-11)1.61011, so this is an excellent result.

http://www.wiredchemist.com/chemistry/data/solubility-product-constants