The elements A and Z combine to produce two different compounds: A_2Z_3 and AZ_2. If 0.15 mole of A_2Z_3 has a mass of 15.9 g and 0.15 mole of AZ_2 has a mass of 9.3 g, what are the atomic masses of A and Z?

1 Answer
Sep 5, 2016

m_"a A" = "26 u"

m_"a Z" = "18 u"

Explanation:

All you have to do here is set up a system of two equations with two unknowns, the molar mass of "A" and the molar mass of "Z".

Once you know the molar masses of the two elements, you can use a simple conversion factor to find their respective atomic masses.

So, you know that 0.15 moles of "A"_2"Z"_3 have a mass of "15.9 g". To make the calculations easier, calculate the mass of one mole of "A"_2"Z"_3

1 color(red)(cancel(color(black)("mole A"_2"Z"_3))) * "15.9 g"/(0.15color(red)(cancel(color(black)("moles A"_2"Z"_3)))) = "106 g"

Notice that one mole of "A"_2"Z"_3 contains

  • two moles of "A", 2 xx "A"
  • three moles of "Z", 3 xx "Z"

If you take a to be the molar mass of "A" and z to be the molar mass of "Z", you can say that

2 * a + 3 * z = "106 g"" " " "color(orange)((1))

Now do the same for "AZ"_2. You have

1 color(red)(cancel(color(black)("mole AZ"_2))) * "9.3 g"/(0.15color(red)(cancel(color(black)("moles AZ"_2)))) = "62 g"

This time, in one mole of "AZ"_2 you have

  • one mole of "A", 1 xx "A"
  • two moles of "Z", 2 xx "Z"

You will thus have

a + 2 * z = "62 g"" " " "color(orange)((2))

Use equation color(orange)((2)) to write

a = 62 - 2z

Plug this into equation color(orange)((1)) to get

2 * (62 - 2z) + 3 * z= 106

124 - 4z + 3z = 106

Rearrange to find

z = 18

This means that you have

a = 62 - 2 * 18 = 26

So, you know that the molar masses of the two elements are

"For A: " "26 g mol"^(-1)

"For B: " "18 g mol"^(-1)

To convert these to atomic masses, use the conversion factor

color(purple)(bar(ul(|color(white)(a/a)color(black)("1 u " = " 1 g mol"^(-1))color(white)(a/a)|)))

You will have

"For A: " m_"a A" = "26 u"

"For B: " m_"a Z" = "18 u"