The empirical formula of butadiene is C2H3. An experimental determination of the molar mass of butadiene yields the value of 54 g/mol. What is the molecular formula of butadiene?

1 Answer
Jan 15, 2016

C4H6

Explanation:

The molecular formula is always a mulitple of the empirical formula; of course the multiple may be one if the molecular formula is the same as the empirical formula.

Given that MF = (EF)n, we simply solve for n using the sum of the constituent atomic masses:

n×(2×12.011+3×1.00794)gmol1 = 54 gmol1

Clearly n = 2.

Molecular formula = 2×C2H3 = C29H37??