What are the gas laws formulas?

2 Answers
Dec 17, 2017

There are a few

Explanation:

Boyle's law:
Ppropto1/VP1V

Charles' law:
VproptoTVT

Pressure law:
PproptoTPT

Avogradro's law
VproptonVn

Ideal gas law:
PV=nRTPV=nRT or PV=NkTPV=NkT

These may also apply:
PV=(Nm< c^2>)/3PV=Nm<c2>3 and 1/2m< c^2>=3/2kT=3/2(RT)/(N_a)12m<c232kT=32RTNa

Key:
PP = pressure (PaPa)
VV = volume (m^3m3)
TT = absolute temperature (KK)
nn = number of moles (molmol)
RR = gas constant (N_a*k) (8.31Jcolor(white)(l)K^(-1)color(white)(l)mol^(-1)8.31JlK1lmol1)
NN = number of atoms/molecules (n*N_anNa)
kk = Boltzmann constant (1.38*10^(-23)Jcolor(white)(l)K^(-1)1.381023JlK1)
mm = mass of one atom/molecule (kgkg)
< c^2><c2> = root-mean-squared speed of atoms/molecules (sqrt((a^2+b^2+c^2+cdots)/N)a2+b2+c2+N) (ms^(-1)ms1)

Dec 17, 2017

You only need one for ideal gases:

color(blue)(|barulstackrel(" ")(" "PV = nRT" ")|)

where:

  • P is pressure in "atm".
  • V is volume in "L".
  • n is mols of ideal gas.
  • R = "0.082057 L"cdot"atm/mol"cdot"K" is the universal gas constant for these pressure and volume units.
  • T is the temperature in "K".

If you wish to utilize other ones, you must examine the question wording and determine the environmental conditions, then set up your initial and final states. This is how you will be expected to do it on exams.

CONSTANT PRESSURE AND MOLS OF GAS

In this case your volume and temperature vary.

PV_1 = nRT_1
PV_2 = nRT_2

Thus, dividing these gives

V_1/V_2 = T_1/T_2

or

color(blue)(V_1/T_1 = V_2/T_2),

known as Charles's Law.

CONSTANT TEMPERATURE AND MOLS OF GAS

In this case your pressure and volume vary.

P_1V_1 = nRT
P_2V_2 = nRT

Thus, we get

color(blue)(P_1V_1 = P_2V_2),

known as Boyle's Law.

CONSTANT PRESSURE AND TEMPERATURE

In this case your volume and mols vary such that your molar volume is constant for the same gas:

PV_1 = n_1RT
PV_2 = n_2RT

Therefore,

V_1/V_2 = n_1/n_2

or

color(blue)(V_1/n_1 -= barV_1 = V_2/n_2 -= barV_2)

otherwise known as Avogadro's principle.

CONSTANT VOLUME AND MOLS OF GAS

Here we have varying pressure and temperature:

P_1V = nRT_1
P_2V = nRT_2

Thus,

P_1/P_2 = T_1/T_2

or

color(blue)(P_1/T_1 = P_2/T_2)

sometimes known as Gay-Lussac's Law.